Organic chemistry – Page 11
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Business
Soapbark branches out to fill essential role in vaccine recipes
The soapbark tree has long been used in traditional medicines, but is now coveted for some of our newest vaccines
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Research
Liquid metal boosts platinum catalyst’s activity 1000 times
Gallium containing single platinum atoms outperforms solid platinum catalysts in electrochemical methanol oxidation
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Research
Carbon fragment’s five atom walk in unprecedented rearrangement reaction
Reaction discovered by accident is a rare case of a room temperature [1,5] carbon shift
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Opinion
Catalogues of complexity
The tangled web of fine chemicals supply frequently throws up surprises
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Research
Electrocatalytic hydrogen atom transfer could give industrial organic synthesis a boost
The new approach – inspired by decades of energy storage research – is selective, efficient and sustainable
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Opinion
From waste to renewable resources
A procedure for breaking the recalcitrant C–C bonds in lignin
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Opinion
An idea that clicked
Bioorthogonal reactions – doing chemistry inside living cells without blasting everything in sight – are no mean feat
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Opinion
Carolyn Bertozzi: ‘Shooting hoops is very meditative’
The celebrated chemical biologist who dreamed of being a rock star before inventing the field of bioorthogonal chemistry
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Feature
The bioorthogonal revolution
A set of reactions operating silently inside live cells or whole animals are lighting up chemical biology and inspiring new medicines, James Mitchell Crow finds
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Research
New family of hollow molecules separates troublesome hydrocarbon mixtures
Meet the cagearenes – 3D frameworks made from aromatic building blocks and methylene groups
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Research
It’s not enough to be 3D and aromatic to be 3D aromatic
Misusing the term 3D aromaticity could put chemists on a slippery slope where the concept loses meaning
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Research
Bottleable but reactive carbocations are powerful hydride abstractors
Fluorinated trityl cations outperform trityl for hydride abstraction reactions
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Feature
Life’s chemistry goes through the looking glass
Chemists were taught that natural systems only use L-amino acids. Andy Extance finds out just how wrong that is proving
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Opinion
Exit strategy
Overcoming a major setback showed Derek Lowe could make it through graduate school
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Research
Spotlight shone on sped up photochemical reactions in droplets
Light can produce ‘hot spots’ in aerosols that supercharge reaction rates
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Research
Automated carbon-13 NMR structure validation program highlights errors atom-by-atom
Introducing a new measure to quantify molecular structural uncertainty
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Research
Molecular ratchet made from only 26 atoms rotates in one direction
Chiral fuel drives molecular machine’s rotation, mimicking fundamental biological processes
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Opinion
Building data systems to break down research silos
Shared schemas could make it a lot easier for researchers to cross discipline boundaries